Satellite ligand effects on magnetic exchange in dimers. A structural, magnetic and theoretical investigation of Cu₂L₂X₄ (L = methylisothiazolinone and X = Cl⁻, Br⁻)

Stefan Coetzee,Mark M. Turnbull,Christopher P. Landee,Jeffrey C. Monroe,Mercè Deumal,Juan. J. Novoa,Melanie Rademeyer

Physical Chemistry Chemical Physics（2023）

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摘要

The orientation of the terminal/satellite L ligands in stacked-dimer Cu2X4L2 polymers is shown to affect the magnetic exchange in and between dimers. This information introduces an additional design tool to tune the magnetic exchange from AFM to FM.

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satellite ligand effects,magnetic exchange,dimers

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Satellite ligand effects on magnetic exchange in dimers. A structural, magnetic and theoretical investigation of Cu2L2X4 (L = methylisothiazolinone and X = Cl−, Br−)

Satellite ligand effects on magnetic exchange in dimers. A structural, magnetic and theoretical investigation of Cu₂L₂X₄ (L = methylisothiazolinone and X = Cl⁻, Br⁻)