Construction of a π-stacked supramolecular framework using a triphenylene-cored metallo-organic cage

Zhilong Jiang,Jun Wang,Mingzhao Chen,Chaolong Tang,He Zhao,Qiangqiang Dong,Wei-Dong Yu,Zhiyuan Jiang,Bangtang Chen,Xiaorui Li,Die Liu,Liao-Yuan Yao,Hui Liu,Ting-Zheng Xie,Tun Wu,Jie Yuan,Kun Wang,Yiming Li,Pingshan Wang

Inorganic Chemistry Frontiers（2023）

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摘要

A pair of enantiomeric tetrahedral cages have been constructed using a hexapod ligand. By utilizing large aromatic triphenylene as the core, the crystal structure of the metallo-cages exhibited a hierarchical packing due to the π–π interaction.

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关键词

supramolecular framework,triphenylene-cored,metallo-organic

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