Dilution enthalpies of the binary systems (LiBO2 + H2O) and (LiB5O8 + H2O) and the ion interactions at 308.15 K

Yuqi Wang,Linxue Yan,Hua Li,Long Li,Yafei Guo,Tianlong Deng

SSRN Electronic Journal（2023）

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摘要

•Microcalorimeter measured the dilution enthalpies of the systems (LiBO2 + H2O) and (LiB5O8 + H2O).•Apparent molar enthalpies of the two aqueous systems were derived via Debye-Hückel limiting law.•The single salt parameters of LiB(OH)4 and LiB5O6(OH)4 were obtained by the Pitzer model.

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关键词

Lithium metaborate,Lithium pentaborate,Dilution enthalpy,Apparent molar enthalpy,Pitzer model

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