Untangling heat transport dynamics using luminescence nanothermometry
Research Square (Research Square)(2022)
摘要
Abstract Temperature touches all aspects of our daily life, including climate, production plants, food storage, transportation, metrology, microelectronics, and medicine, and is a major factor dictating performance of nanotechnologies.1-4 However, while the heat transfer is well understood in bulk, neither experimental nor theoretical models provide a complete picture of the thermal dynamics at the nanoscale.5-7 Here, in situ luminescence thermometry is used to probe the heat propagation taking place within lanthanide (Ln3+)-doped upconverting nanoparticles (UCNPs). We have designed UCNPs with Er3+ and Tm3+ thermometric layers positioned at different locations relative to their surface, varying the distance a heat wave travels before encountering the layers. Despite being separated only by a few tens of nanometers, the thermometric layer closer to the surface of UCNPs detects temperature increase much earlier than the one located at the center – yielding the heat propagation speed in UCNPs ~1.3 nm/s. The UCNPs featuring the two thermometric layers in a single nanostructure confirmed the above result and allowed us to uncover diffusive and non-diffusive (ballistic) heat transport regimes, as well as their interplay and complex heat exchange dynamics taking place in colloidal nanoparticles (nanofluids) at a room temperature.
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关键词
heat transport dynamics,luminescence
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