Catalytic cavities control oligomer length

Nature Synthesis(2023)

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摘要
Catalytic templates produce oligomers of a defined length, moving beyond stoichiometric ratios of template to substrate. Bifunctional catalytic macrocycles with a defined cavity have a high affinity for the monomer but not the oligomer, enabling high-turnover oligomer synthesis.
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关键词
Catalyst synthesis,Molecular capsules,Chemistry/Food Science,general
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