Photoluminescent ellipsometric circular dichroism

A novel spectroscopic technique, photoluminescent ellipsometric circular dichroism (PECD), which distinguishes all radiative electronic transitions related to molecular chiral centers. Additionally, it is proposed as comple-mentary to the ellipsometric Raman spectroscopy (ERS) technique, thus establishing a relationship between vibrational modes and electronic transitions, associated with molecular chiral centers. In this way, PECD turns into a powerful technique for chiral material characterization. The PECD technique was performed on a chiral oligomer (1R,2R)-diiminocyclohexane, and its derivative polymer. A complete photophysical characterization in solution was performed to corroborate the new PECD technique.