Insoluble oxalates modified K₂XF₆:Mn⁴⁺ (X = Ti, Ge, Si) red-emitting phosphors exhibiting excellent moisture resistance and luminescence for warm white light-emitting diodes

Lidan Han,Rui Zhang, Yanhui Chen, Chen Jiang,Xiaoli Wu

Materials Advances（2023）

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摘要

Insoluble MC2O4 (M = Ca, Sr, Ba, Mn) particles were modified on the K2XF6:Mn4+ (X = Ti, Ge, Si) surfaces, which prevent the hydrolysis of internal [MnF6]2− groups and promote the reduction of exposed Mn4+ ions into Mn2+ ones.

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Insoluble oxalates modified K2XF6:Mn4+ (X = Ti, Ge, Si) red-emitting phosphors exhibiting excellent moisture resistance and luminescence for warm white light-emitting diodes

Insoluble oxalates modified K₂XF₆:Mn⁴⁺ (X = Ti, Ge, Si) red-emitting phosphors exhibiting excellent moisture resistance and luminescence for warm white light-emitting diodes