Facile immobilization of P^NN^NP-Pd pincer complexes in MFU-4l-OH and the effects of guest loading on Lewis acid catalytic activity

Jordon S. Hilliard,Casey R. Wade

Dalton Transactions（2023）

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摘要

A Brønsted acid–base reaction has been used to encapsulate palladium diphosphine pincer complexes (PNNNP-PdBF4) in the benzotriazolate MOF MFU-4l-OH. The Lewis acid catalytic activity increases with decreasing catalyst density.

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Facile immobilization of PNNNP-Pd pincer complexes in MFU-4l-OH and the effects of guest loading on Lewis acid catalytic activity

Facile immobilization of P^NN^NP-Pd pincer complexes in MFU-4l-OH and the effects of guest loading on Lewis acid catalytic activity