Multiple CO2 reduction mediated by heteronuclear metal carbide cluster anions RhTaC2−
Dalton Transactions(2022)
摘要
A RhTaC2− cluster can reduce four CO2 molecules consecutively. The pivotal roles of Rh–Ta synergy and the C2 ligand in driving CO2 reduction were rationalized. A fundamental strategy to alleviate carbon deposition in the CO2 atmosphere was provided.
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