Anticancer half-sandwich Ir(iii) complex and its interaction with various biomolecules and their mixtures – a case study with ascorbic acid

Lukáš Masaryk,Jakub Orvoš,Karolina Słoczyńska,Radovan Herchel,Ján Moncol,David Milde,Petr Halaš,Radka Křikavová,Paulina Koczurkiewicz-Adamczyk,Elżbieta Pękala,Róbert Fischer,Ivan Šalitroš,Ivan Nemec,Pavel Štarha

Inorganic Chemistry Frontiers（2022）

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摘要

An anticancer azo bond-containing half-sandwich Ir(iii) complex oxidizes ascorbate to dehydroascorbate, and ascorbate recovers in the presence of reduced glutathione.

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