Geology, Geochronology and Geoenergy of Sedimentary Basins: Insights from the Midland Valley of Scotland, UK

The Midland Valley Basin of Scotland (MVS) is a major NE-SW trending, fault-bounded sedimentary basin in central Scotland, UK, comprised predominantly of Carboniferous and Devonian sedimentary rocks. Changing palaeo-environments of the MVS produced alternating successions of sandstone, siltstone, mudstone, limestone and coal. The MVS also experienced folding, fault inversion and development of a widespread unconformity during the latest Carboniferous culmination of the Variscan Orogeny and minor tectonic events thereafter. The MVS’ geological resources played a major role in driving Scotland’s economic, industrial, and cultural development in the 19th - 20th. The region was heavily exploited for coal and hydrocarbon energy resources and material for construction, manufacturing, and agriculture. The MVS basin remains as relevant in the 21st century having been identified as a viable source of low-carbon geo-energy resources (e.g., geothermal energy) and potential for subsurface energy storage (Heinemann et al., 2019). While the geology of the MVS has been well-studied, thermal and burial history reconstructions have typically relied on techniques focused on the maturation of organic matter (e.g., vitrinite reflectance, VR), which lack quantitative information on timing. Moreover, tracing sediment provenance can be challenging but crucial for understanding the tectonic evolution of the surrounding source region. Here, we present the results of a geochronological and thermochronological investigation of the MVS basin designed to better understand sediment pathways to the basin from surrounding upland regions and the post-depositional thermal history of the MVS. Our data includes zircon and apatite U-Pb data and apatite fission-track (AFT) data from across the basin and AFT data from a UK Geoenergy Observatories borehole in Glasgow. With our U-Pb data, we identify distant source areas in Greenland, more local source areas in the Scottish Highlands, and recycling of older sedimentary rocks and reworked material in the basin that change through the tectono-magmatic evolution of the basin. Our AFT data and associated thermal history modelling identify three main thermal events: i) Carboniferous-Permian heating; ii) Permian-Mesozoic cooling, and iii) relatively rapid Cenozoic cooling (McKenna, 2021; Hattie, 2021). These are attributed to post-Carboniferous burial followed by post-Permian exhumation. However, ambiguity in some of our models suggests some heating in the Mesozoic may have occurred and, due to the limitations on the temperature sensitivity of the AFT technique, the timing and rate of Cenozoic cooling is poorly resolved. Through our modelling we explore the influence changing palaeo-geothermal gradients has on our thermal history and whether the lower temperature thermochronometer apatite (U-Th)/He can better resolve the most-recent cooling event. Heinemann, N., Alcalde, J., Johnson, G., Roberts, J. J., McCay, A. T., & Booth, M. G. (2019). Low-carbon GeoEnergy resource options in the Midland Valley of Scotland, UK. Scottish Journal of Geology, 55(2), 93-106. McKenna, Eamon (2021) The Provenance and thermal histories of the Carboniferous Midland Valley of Scotland, PhD thesis, University of Glasgow. Hattie, Andrew (2021) Constraining the post-burial history of the central Midland Valley of Scotland using apatite fission track analysis: implications for geothermal energy. MSc(R) thesis, University of Glasgow.