Artificial helix supramolecule by doubly p-xylyl bridged bis(ZnII–cyclen) (cyclen = 1,4,7,10-tetraazacyclododecane)

Yoshimi Ichimaru,Koichi Kato,Kirara Sugiura,Risa Isomura,Haruto Fujioka,Tohru Koike, Sayuri Fujii-Kishida,Masaaki Kurihara,Yoshihiro Yamaguchi,Wanchun Jin,Masanori Imai,Hiromasa Kurosaki

Inorganic Chemistry Communications（2023）

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摘要

•p-Xylene doubly-bridged di-zinc complex, p,p-bis(ZnII–cyclen), was synthesized.•In the crystal structure, p,p-bis(ZnII–cyclen) was built into helix-like structure.•The substituent position of the xylene bridge affects the supramolecular structure.

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关键词

artificial helix supramolecule,bisznii–cyclen,p-xylyl

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