Combined effect of Ru on the oxidation behavior and microstructure stability of a single crystal superalloy

The isothermal oxidation behavior and the microstructure stability was studied at 900 & DEG;C, 1000 & DEG;C and 1100 & DEG;C of the two alloys with and without Ru. The curves of oxidation weight gain show that the oxidation resistance decreases sharply with the addition of Ru. A multilayered scale formed on the alloy surface, and it generally consisted of an external layer of NiO, an intermediate layer of spinel and an Al2O3 inner layer. The oxidation rate at 1100 & DEG;C is significantly higher than that at the other two temperatures due to more serious cracking and peeling of oxide scale. Compared with Ru-free alloy, the oxide layer of Ru-containing alloy is thicker and the oxide layer spallation more seriously. The oxide of Ru was found in the spinel layer and the vaporization of the oxide makes the scale spallation. Surprisingly, a large number of TCP phases were found in alloy matrix, especially in 2Ru alloy. This indicates that poor oxidation resistance will lead to a decline in microstructure stability. & COPY; 2023 Published by Elsevier B.V. This is an open access article under the CC BY-NC-ND