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Efficient Electrochemical Decomposition of Sulfamethoxazole Using a Novel Free-Standing TiN Anode

Guoshuai Liu,Ming Liu,Han Shi,Hao Jia,Hua Zou, Nan Tao

Sustainable Horizons（2023）

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Abstract
•Novel free-standing TiN as a ceramic anode was prepared by spark plasma sintering (SPS) method.•TiN anode could generates •OH sufficiently rather than O2, making TiN an excellent material for the mineralization of recalcitrant SMX.•DFT and LC-MS/MS results demonstrated that the degradation pathway of SMX was mediated by •OH through the H-abstraction and electron-transfer pathway.
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Key words
TiN,Electrochemical oxidation,Sulfamethoxazole,Hydroxyl radical,Density functional theory
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