Heterogeneous Metallaphotocatalytic C(sp²)-C(sp³) Cross-Coupling Reactions with Integrated Bipyridyl-Ni(II)-Carbon Nitride

A fullyheterogeneous metallaphotocatalytic C-Ccross-couplingof aryl/vinyl halides with alkyl/allyltrifluoroborates has been developedby employing integrated bipyridyl-Ni-(II)-carbon nitride as a stableand recyclable bifunctional catalyst. This visible-light-mediatedheterogeneous protocol allows for the sustainable synthesis of diversevaluable diarylmethanes and allylarenes in high efficiency.