Polycrystal Li 2 ZnTi 3 O 8 /C anode with lotus seedpod structure for high-performance lithium storage.

Lotus-seedpod structured LiZnTiO/C (P-LZTO) microspheres obtained by the molten salt method are reported for the first time. The received phase-pure LiZnTiO nanoparticles are inserted into the carbon matrix homogeneously to form a Lotus-seedpod structure, as confirmed by the morphological and structural measurements. As the anode for lithium-ion batteries, the P-LZTO material demonstrates excellent electrochemical performance with a high rate capacity of 193.2 mAh g at 5 A g and long-term cyclic stability up to 300 cycles at 1 A g. After even 300 cyclings, the P-LZTO particles can maintain their morphological and structural integrity. The superior electrochemical performances have arisen from the unique structure where the polycrystalline structure is beneficial for shorting the lithium-ion diffusion path, while the well-encapsulated carbon matrix can not only enhance the electronic conductivity of the composite but also alleviate the stress anisotropy during lithiation/delithiation process, leading to well-preserved particles.