A change of direction through trans -bis-silylation of alkynes

Nature Synthesis（2023）

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摘要

The activation of a Si–Si bond and its subsequent trans- addition across an alkyne substrate is a challenge. Now, a Pd-catalysed process for the trans -bis-silylation of terminal alkynes is reported, using a quinoline-substituted disilane reagent.

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trans-bis-silylation

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