Numerical simulation of the impact of different cushion gases on underground hydrogen storage in aquifers based on an experimentally- benchmarked equation-of-state

Underground hydrogen storage (UHS) in geological formations is a promising technology for large-scale hydrogen energy storage. In this study we focus on UHS in saline aquifers. Although lessons were learned from similar studies, including geological carbon sequestration and underground gas storage, the unique thermodynamic and physical properties of hydrogen distinguish UHS from the other subsurface storage projects. We developed a two-phase, three-component reservoir simulator, which incorporated essential physics based on the fully coupled multi-physics framework of the Delft Advanced Reservoir Simulation (DARSim). Properties of fluid mixtures were computed using the GERG-2008 equation of state (EoS), in which the parameters were determined by fitting laboratory data. The simulation results demonstrated the impact of different cushion gases (CO2, CH4, and N2) on UHS. Most hydrogen stayed in the gaseous phase at the top of the aquifer when CH4 and N2 were used as the cushion gas. Conversely, hydrogen-rich fingers were observed in the aqueous phase when CO2 was used as the cushion gas, because dissolved CO2 increased brine density, leading to density-driven downward convection which was favorable for hydrogen dissolution into the aqueous phase. The highest purity of produced hydrogen was observed when CO2 was used as the cushion gas, whereas using CH4 and N2 as the cushion gas was favorable for the hydrogen production rate and mobility. This work is the first study that utilizes an EoS-based reservoir simulator to investigate hydrogen's flow patterns and interactions with cushion gases in an underground storage system. Specifically, the productivity and retrievability of hydrogen in a two-phase, three-component UHS system were analyzed in detail. The developed reservoir simulation tool and research findings from this study will be valuable to support decision making in practical UHS projects.(c) 2023 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved.