Oxygen vacancies induced by Ce3+/Ce4+ doping mediate the formation of Bi0/Bi2O3/Bi2O2.75 nanosheets for visible light-driven photocatalytic degradation of lignin

Chemical Engineering Journal(2023)

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摘要
•Oxygen vacancies induced by Ce doping mediate the formation phase transition rearrangement of δ-Bi2O3 to form tetragonal phase Bi2O2.75.•In-situ reduction of Bi3+ produces Bi0 to prepare S-type heterojunction Bi0/Bi2O3/Bi2O2.75 ultrathin nanosheets.•The S-type charge transfer mechanism of Bi0/Bi2O3/Bi2O2.75 heterojunction has been analyzed through experiments and DFT calculations.
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关键词
Bi/Bi2O3/Bi2O2.75,Oxygen vacancies,Photocatalytic degradation,DFT,Lignin
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