Liquids with Permanent Macroporosity
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION(2023)
摘要
Permanent macropores (>50 nm) had not been reported in the liquid state until a recent report by Tao Li and co-workers describing a synthetic strategy to form a porous liquid with dual micro-macroporosity. This is prepared by producing hierarchically porous particles that are surface coated and fluidised by dispersion. Surface micropores enable permanent porosity by steric exclusion of the fluid phase. The material has a considerable water uptake capacity (27 % w/w) due to large (480 nm) unoccupied macropores. This also enables switching of thermal conductivity on uptake of water. These are new properties translated from porous solids to the liquid state.
更多查看译文
关键词
Gas Adsorption, Macropore, Metal-Organic Framework, Porous Liquid, Thermal Conductivity
AI 理解论文
溯源树
样例
生成溯源树,研究论文发展脉络
Chat Paper
正在生成论文摘要