Tip-enhanced Raman Imaging of Plasmon-Driven Dimerization of 4-Bromothiophenol on Nickel-Decorated Gold Nanoplate Bimetallic Nanostructures.

We used tip-enhanced Raman spectroscopy (TERS) to examine plasmon-driven dimerization of 4-bromothiophenol (4-BTP) into thiophenol (TP) and 4,4'-biphenyldithiol (4,4'-BPDT) on Au and Ni@AuNPs. TERS revealed that cross-coupling of these molecular reactants into 4,4'-BPDT occurred primarily on Ni nano islands rather than the surrounding Au on the surface of Ni@AuNPs.