Self-assembled Frameworks Solid with Turbostratic Stacked Crystalline Layers -- A Frustrated 3D Crystal Lattice
arXiv (Cornell University)(2023)
摘要
Solid materials possess both long-range order and some degree of disorder are critical for understanding the nature of crystal and glassy state, but how to controllable introduce specific type of disorder into a crystalline material is a big challenge. Our previous work indicated that weakening the inter-layer interaction is an effective strategy to import disorders between the layers.Here, we illustrated that the inter-layer interaction can be weakened to around 1/60 of that of graphite in the self-assembled material, a two-dimensions frameworks formed by B-C-T-A with Cu nodes, which has an obvious layered-structure.
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关键词
turbostratic stacked crystalline,frameworks,self-assembled
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