The Efficient Removal of Ibuprofen, Caffeine, and Bisphenol A Using Engineered Egusi Seed Shells Biochar: Adsorption Kinetics, Equilibrium, Thermodynamics, and Mechanism.

Contaminants of emerging concern (CECs), also known as micropollutants, have been recognized in recent years as substantial water pollutants because of the potential threats they pose to the environment and human health. This study was aimed at preparing biochar (BC) based on egusi seed shells (ESS) with well-developed porosity and excellent adsorption capacity towards CECs including ibuprofen (IBP), caffeine (CAF), and bisphenol A (BPA). BC samples were prepared by pyrolysis at different temperatures (400 to 800 °C) and were characterized using nitrogen sorption, FTIR, powder X-ray diffraction (PXRD), SEM/EDS, elemental analysis, and thermal analysis. The nitrogen sorption and SEM results showed that the textural properties were more prominent as the pyrolysis temperature increased. The BC sample obtained at 800 °C which exhibited the largest specific surface area (688 m2/g) and the highest pore volume (0.320 cm3/g) was selected for the adsorption study of CECs. The kinetic study shows that the adsorption equilibrium of CAF and BPA was faster than that of IBP. The pseudo-first- and pseudo-second-order kinetic models best fitted the adsorption data. The Langmuir maximum monolayer adsorption capacities of biochar were found to be 180, 121, and 73 mg/g respectively for IBP, CAF, and BPA. The thermodynamic study shows that the adsorption process was spontaneous and endothermic for the three CECs. The results of the adsorption and the analysis of BC after adsorption showed that hydrogen bonding, van der Waals, π-π, n-π interactions, and pore filling were involved in the adsorption mechanism. The prepared biochar BC from ESS displayed a large surface area and good morphology and significantly promotes adsorption of CECs and good efficiency on synthetic effluent. Finally, it offers a low-cost and cleaner production method.