Zinc 8-aminotrihydroquinolines appended with pendant N-diphenylphosphinoethyl arms as exceptionally active catalysts for the ROP of ε-CL

Catalysis Science & Technology(2022)

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摘要
Through activation with LiCH 2 SiMe 3 or LiN(SiMe 3 ) 2 , zinc( ii ) chloride complexes bearing 5,6,7-trihydroquinolin-8-amines appended with pendant diphenyl phosphine units displayed remarkable catalytic activity for ROP of ε-caprolactone.
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关键词
active catalysts,zinc
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