B(C₆F₅)₃-catalyzed β-C(sp³)–H alkylation of tertiary amines with 2-aryl-3H-indol-3-ones

Changpeng Zou,Tao Ma,Xiu-Xiu Qiao,Xixi Wu,Gan‐Peng Li, Yan He, Zhao Xin

Organic and Biomolecular Chemistry（2023）

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摘要

Herein, we describe a B(C 6 F 5 ) 3 -catalyzed redox-neutral β-functionalization of tertiary amines with cyclic-ketimines, achieving various 1,3-diamines containing the indolin-3-one moiety via the borrowing hydrogen strategy.

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关键词

tertiary amines,alkylation

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B(C6F5)3-catalyzed β-C(sp3)–H alkylation of tertiary amines with 2-aryl-3H-indol-3-ones

B(C₆F₅)₃-catalyzed β-C(sp³)–H alkylation of tertiary amines with 2-aryl-3H-indol-3-ones