Anatomy of real intermediate state-subtraction scheme

We study the origin of the real intermediate state subtraction problem and compare its different solutions. We show that the ambiguity in subtraction schemes arises from the on-shell approximation for the 2-point functions that reduces the Schwinger-Dyson equations to the Boltzmann limit. We also suggest a new subtraction scheme which, unlike the earlier definitions, never leads to negative scattering rates. This scheme also quantifies the validity of the on-shell limit in terms of an effective one-particle weight function R(Delta), where Delta measures the region around the resonance associated with the real state.