A mass transfer cavitation model for the numerical flow simulation of binary alkane mixture segregation

Based on the Rayleigh bubble dynamics equation a mass transfer model for cavitation of binary alkane mixtures is presented. Raoult's and Dalton's law, simple mixing rules, and an accurate Equation of State are utilized. The model is implemented into an in-house CFD code. For solver validation pure species literature cases are taken. The method is applied to a lighter n-octane/n-heptane and a heavier n-dodecane/n-heptane mixture in a rarefaction tube and a hydrofoil test case. Segregation of the species is observed during cavitation due to their different mass transfer rates. While for the lighter mixture, mass transfer of both species only moderately deviates, a significantly higher mass transfer of n-heptane compared to n-dodecane is observed for the heavier mixture, where the saturation pressure differs two orders of magnitude between the mixture ingredients. The strong segregation of the heavier mixture is associated with a predominant amount of n-heptane in the vapor phase. As a consequence, vapor composition is strongly affected by the volatilities of mixture ingredients.