Triple role of thiocyanate-containing protic ionic liquids in chemodivergent ring-opening of 1,3-indanedione-derived donor-acceptor cyclopropanes

Nina K. Ratmanova,Ivan A. Andreev,Vitaly A. Shcherbinin,Olga A. Ivanova,Irina I. Levina,Victor N. Khrustalev,Igor V. Trushkov

JOURNAL OF MOLECULAR LIQUIDS（2023）

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摘要

Triple-role thiocyanate-containing protic ionic liquids (PILs) were employed as a regenerable solvent, a Bronsted acid catalyst, and a source of the nucleophile for the ring-opening of 1,3-indanedione-based donor-acceptor cyclopropanes.

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关键词

Ionic liquids, (Iso)thiocyanates, Small ring systems, Donor-acceptor cyclopropanes, Nitrogen heterocycles

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