New Insight into Opposite Oxidation Behavior in Acetone and Propane Catalytic Oxidation over CoMn Based Spinel Oxides

Cangpeng Shan,Yan Zhang,Qian Zhao,Jianbo Li,Yunchong Wang,Rui Han,Caixia Liu,Qingling Liu

CHEMICAL ENGINEERING JOURNAL（2023）

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摘要

•CoMn spinel and Zn-substituted CoMn spinel oxides were fabricated.•Differences in reaction mechanism of acetone and propane oxidation were revealed.•Lattice oxygen activity and oxygen activation capacity promoted acetone deep oxidation.•High valence Mn species facilitated C-H dissociation and C3H7 activation of propane.

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关键词

VOC oxidation,Spinel oxide,Acetone,Propane,Substitution

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