Utilization of palm residues for biochar production using continuous flow pyrolysis unit

Mahmoud Younis, Hesham A. Farag, Abdulla Alhamdan, Galal Aboelasaad,Assem I. Zein El-Abedein,Reham M. Kamel

Food Chemistry: X(2023)

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摘要
Biochar is a carbonaceous solid substance produced by heating biomass without using air. This research aimed to create and evaluate local carbonization pyrolysis using a screw conveyor and filtration equipment. Date palm frond (DPF) biochar was studied and tested at pyrolysis temperatures of 320, 390, and 460 degrees C, as well as feeding rates of 60, 90, and 120 kg/h. The physicochemical parameters of DPF biochar were evaluated using SEM and FTIR. When the pyrolysis temperature was raised from 320 to 450 degrees C, and the feed rates were reduced from 120 to 60 kg/h, the biochar yield of DPF and volatiles fell. At 460 degrees C and 60 kg/h, the maximum ash and fixed carbon content were 11.73 and 77.61 %, respectively. As the feed rate decreased and the temperature increased, the H and O values (1.96 and 2.62 %, respectively) of DPF biochar decreased considerably; the C and N values (83.60 and 0.24 %, respectively) trended in opposite directions. The BET surface area and pore volume increased as a result of the micropore surface area and volume at higher temperatures and lower feeding rates, but water holding capacity increased from 6.04 gwater/10 g at 320 degrees C to 6.78 gwater/10 g at 390 degrees C (60 kg/h). The results showed that the heating temperature increased and the feeding rate decreased; phosphorus) P(and magnesium (Mg) increased significantly, whereas the levels of potassium (K) and calcium (Ca) showed a non-significant increase. Furthermore, as the pyrolysis temperature increased, pH and EC increased from 7.90 to 10.96 and 2.91 to 4.25 dSm(-1), respectively, while CEC declined; however, there were no significant changes in CEC. DPF biochar demonstrated enhanced macro porosity and surface area at 460 degrees C and 60 kg/h, making it acceptable for agricultural use as a soil supplement.
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关键词
Date palm fronds,Biochar,Pyrolysis,Continuous flow,Physical and chemical properties
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