Kinetic enantio-recognition of chiral viologen guests by planar-chiral porphyrin cages

Pieter J. Gilissen,Quentin Duez, Guilherme L. Tripodi, Magda M. J. Dekker,Jiangkun Ouyang,Kais Dhbaibi,Nicolas Vanthuyne,Jeanne Crassous,Jana Roithová,Johannes A. A. W. Elemans,Roeland J. M. Nolte

Chemical communications (Cambridge, England)（2023）

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摘要

The kinetic enantio-recognition of chiral viologen guests by planar-chiral porphyrin cage compounds, measured in terms of ΔΔ‡on, is determined by the planar-chirality of the host and influenced by the size, as measured by ion mobility-mass spectrometry, but not the chirality of its substituents.

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