Femtosecond Laser Ablation of a Bulk Graphite Target in Water for Polyyne and Nanomaterial Synthesis

Laser ablation of a bulk graphite target in water using femtosecond laser pulses (pulse width <= 190 fs) was performed to investigate the synthesis of polyynes and carbon-based nanomaterials and compare them with the well-studied cases of longer pulse (picosecond or nanosecond) ablations. The laser ablation products were characterized using UV-vis absorption spectroscopy, Raman spectroscopy, X-ray diffraction, and transmission electron microscopy, whereas the induced plasma plumes were characterized using laser-induced breakdown spectroscopy. Carbon-based nanomaterials and short-chain polyynes (C6H2 and C8H2) are formed in the solutions as proven by their characteristic absorption band at similar to 262 nm and peaks in the region of 190-240 nm as well as at around 2100 cm(-1) in the Raman spectra, respectively. Polyynes (C8H2) are present in the solutions that are produced under an ablation that is carried out in two intervals with a short pause between them, which is contrary to a continuous ablation that is performed for the same total time duration. The ablation products have a hexagonal graphite crystal structure. The carbon-based nanomaterials consist of large non-spherical and small spherical nanoparticles as well as sheet-like structures. The results of the study were compared with previous studies and discussed based on those studies.