Facile fabricated transparent anti-smudge coating with high hardness and excellent flexibility from MTQ and branched silicone resins

The demand for high-transparent functional coatings with glass-like hardness, polymer-like flexibility, and anti smudge properties has increased significantly, especially for foldable touchscreens. However, it is challenging to achieve all the required properties in a coating because the realization of these properties may conflict with each other. In this study, we present a facile method for preparing a special organic-inorganic hybrid coating by utilizing epoxy MTQ silicone resins and amine-terminated hyperbranched polysiloxane (HPSi). The chemical structure of the MTQ resin was fine-tuned to obtain the optimal M/T/Q ratio, and a novel HPSi with rich crosslinking sites and excellent flexibility was prepared as the curing agent. The resulting hybrid network imparted the coating with exceptional hardness (pencil hardness, 7-9H) and excellent flexibility (<2 mm bend diameter). In addition, by modifying the MTQ resin with fluorosilane, the surface energy of the coating was reduced to 14.8 +/- 0.4 mJ/m(2) and its anti-smudge and self-cleaning properties were improved without sacrificing the transparency of the coating (99.4 % at 550 nm). Notablely, even after 1000 cycles of steel wool abrasion, these coatings still maintain their outstanding performance. This study provides a promising strategy for the development of hard, flexible, and anti-smudge coatings suitable for foldable displays and other related fields.