Ruthenium(II)-Catalyzed S(II)-Directed Aromatic C-H Allylation with Vinylaziridines

The ruthenium-catalyzed reaction of aryl methyl thioethers with vinylaziridines affords ortho-position mono- or bis-allylation products depending on substituents on the phenyl rings of sulfide substrates or the ratio of reactants. The reaction also features mild reaction conditions, good product yields, wide scope of substrates, good compatibility of functional groups, and the selective formation of E-configurated C-C double bonds.