Excellent magnetocaloric effect near 282 K of a Fe87Ce6Pr4B3 metallic glass ribbon

Q. Wang, D. Ding, B. Z. Tang, P. Yu, J. L. Yao,L. Xia

JOURNAL OF NON-CRYSTALLINE SOLIDS(2024)

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摘要
We reported the excellent magnetocaloric effect near 282 K of a Fe87Ce6Pr4B3 metallic glass in this paper. The Fe87Ce6Pr4B3 metallic glass (MG) was fabricated into the shape of ribbon with typical amorphous characteristics in its X-ray diffraction pattern , differential scanning calorimetry curve. The MG is soft magnetic at 200 K (far below its Curie temperature (Tc -282 K)) and paramagnetic at 380 K (well above its Tc). The Fe87Ce6Pr4B3 glassy ribbon shows rather high peak of magnetic entropy change (-Delta Smpeaks 3.95 J/(kg x K)) near 282 K under 5 T, which is the highest amongst the Fe-based MGs with Tc around 282 K. The high -Delta Smpeak near 282 K enables it to be employed for the construction of several amorphous hybrids that present flattened -Delta Sm profile. The high average -Delta Sm from -282 K to -315 K of the amorphous hybrids make them better candidates for the high-efficiency refrigerants of the household magnetic air-conditioner.
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关键词
Metallic glass,Magnetocaloric performance,Refrigeration capacity,Table -like magnetic entropy change profile
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