Synergistically enhanced Si3N4 /Cu heterostructure bonding by laser surface modification

A bonding approach based on laser surface modification was developed to address the poor bonding be-=tween Si3N4 ceramic and Cu. The bonding mechanism in Si3N4/Cu heterogeneous composite structure fabricated by laser modification-assisted bonding is examined by means of scanning/transmission electron microscopy and thermodynamic analysis. In the bonding process under laser modification, atomic intermixing at the interface is confirmed, as a result of the enhanced diffusion assisted by the dissociation of Si3N4 ceramic by laser. The dissociating Si precipitations on the surface, as well as the formation of micro-pores interfacial structure, would be the key concept of the bonding, by which the seamless and robust heterointerfaces were created. By controlling the laser-modifying conditions, we can obtain a reliable heterostructure via the optimization of the trade-off of the surface structure and bonding strength, as determined by the laser-modified surface prior to bonding. The maximum structure depth and S ratio at the Si3N4 surface were produced at a laser power of 56 W, corresponding to the maximal shear strength of 15.26 MPa. It is believed that the further development of this bonding technology will advance power electronic substrate fabrication applied in high-power devices. (c) 2023 Published by Elsevier Ltd on behalf of The editorial office of Journal of Materials Science & Technology.