A copper-catalyzed B–H bond insertion reaction of azide–ynamide with borane adducts via α-imino copper carbenes

Chen-Yong Weng,Guangyu Zhu,Bo‐Han Zhu,Peng‐Cheng Qian,Xin‐Qi Zhu,Jin‐Mei Zhou,Long‐Wu Ye

Organic chemistry frontiers（2022）

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摘要

A new copper-catalyzed B–H bond insertion into α-imino copper carbenes generated from azide–ynamide cyclization has been developed, leading to a facile and practical synthesis of a series of α-boryl amidines.

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关键词

borane adducts,azide–ynamide,copper-catalyzed

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