Engaging DBFO as a C1N1 “two-atom synthon” in [3 + 2] cycloaddition reaction: synthesis of the energetic material 5-azidotetrazolate 1N-oxide

Yong Hu,Xiaojun Wang, Wenxiang Dong,Yu-fan Bi,Zu-Jia Lu, Weipeng Cao,Jianguo Zhang,Qi Zhang, Dong Chen

Organic chemistry frontiers（2021）

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摘要

Employing 1,1-dibromoformaloxime as a novel C1N1 “two-atom synthon” for the synthesis of tetrazole-based energetic materials via an intramolecular [3 + 2] annulation in aqueous solution.

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关键词

cycloaddition reaction,synthesis,c1n1,two-atom

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