Colossal negative thermal expansion in a cucurbit[8]uril-enabled uranyl-organic polythreading framework via thermally induced relaxation

Qiu‐yan Jin,Yuanyuan Liang,Zhi‐Hui Zhang, Lingheng Meng,Jun-Shan Geng,Kexin Hu,Jipan Yu,Zhifang Chai,Lei Mei, Wenjing Shi

Chemical Science（2023）

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摘要

A highly flexible uranyl-organic polythreading framework enabled by cucurbit[8]uril-based host–guest complexation exhibits remarkable negative thermal expansion behaviour through a relaxation-related mechanism.

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关键词

colossal negative thermal expansion,]uril-enabled,uranyl-organic

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