Visible-Light-Promoted Palladium-Catalyzed Cross-Coupling of Iodocarboranes with Disulfides and Phenylselenyl Chloride

CHINESE JOURNAL OF CHEMISTRY(2024)

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摘要
This work describes a general method for the synthesis of a series of sulfenylated and selenylated carboranes at room temperature using readily available iodocarboranes as starting materials via boron-centered carboranyl radicals. Such hypervalent boron radicals are generated by a visible-light-promoted Pd(0)/Pd(I) pathway. They are useful intermediates and can be trapped by disulfides and phenylselenyl chloride for the convenient construction of B-S/Se bonds.
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关键词
Carborane,Sulfenylation,Selenylation,B-I activation,Radical,Photocatalysis,Boron,Selectivity
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