Cyperus pangorei porous carbon electrodes for the sustainable symmetric supercapacitor application

ENERGY STORAGE(2024)

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摘要
Efficiently addressing natural biowaste has the potential to effectively mitigate pressing environmental concerns. Given the growing demand for energy, it is imperative to identify a safe and environmentally friendly method for producing biowaste-based porous carbon (PC). Biowaste serves valuable carbon sources for the cost-effective production of efficient PC materials. In this study, we focus on ongoing research aimed at converting a small-scale industrial waste of Cyperus pangorei, into PC. To achieve this, we employed a simple and eco-friendly approach, optimizing the process at four different temperatures to enhance its suitability for supercapacitor applications. By subjecting the Cyperus pangorei waste to a two-step chemical activation process using potassium hydroxide (KOH) at 800 degrees C (referred to as CPC8), we obtained a PCs with a well-defined pore matrix, exhibiting a surface area of 711.2 m(2)g(-1). The resulting PC exhibited 194.6 Fg(-1) (0.5 Ag-1) of specific capacitance when tested in a 1 M Na2SO4 aqueous electrolyte. The galvanostatic study demonstrated remarkable 88.5 Whkg(-1) of energy density at 1.7 kWkg(-1) power density, along with a capacitance retention rate of 97.9% at 5000th cycle (8 Ag-1). Furthermore, electrochemical impedance study revealed 0.053 Omega of internal resistance, indicating enhanced ionic diffusion. Based on the excellent performance characteristics exhibited by CPC8, its practical application in supercapacitors holds great promise.
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关键词
biowaste derived carbon,high energy density,industrial biowaste,symmetric supercapacitor
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