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Copper-Catalyzed Synthesis of -Keto Sulfones from Enol Silyl Ether and Sodium Arylsulfinates

CHINESE JOURNAL OF ORGANIC CHEMISTRY(2023)

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摘要
beta-Keto sulfones are an important group of sulfur-containing compounds and intermediates for organic synthesis, which are widely used in the construction of natural products and various important organic compounds. A method for the rapid synthesis of beta-keto sulfones catalyzed by copper bromide from enol silyl ether and sodium arylsulfinates is developed, which has the advantages of simple operation, mild conditions and short reaction time.
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关键词
beta-keto sulfone,copper catalysis,enol silyl ether,sodium arylsulfinate
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