The carbon chain growth during the onset of CVD graphene formation on γ-Al₂O₃ is promoted by unsaturated CH₂ ends

Qi Zhao,Masanori Yamamoto,Kaoru Yamazaki,Hirotomo Nishihara,Rachel Crespo‐Otero,Devis Di Tommaso

Physical Chemistry Chemical Physics（2022）

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摘要

Atomistic calculations reveal the steps controlling the early stages of graphene growth on alumina, including the activation of CH 4 and the formation of the reactive CH 2 * intermediate that couple to form linear C n H 2 n * ( n = 2–6) and cyclic C 6 species.

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graphene formation,carbon chain growth,cvd

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The carbon chain growth during the onset of CVD graphene formation on γ-Al2O3 is promoted by unsaturated CH2 ends

The carbon chain growth during the onset of CVD graphene formation on γ-Al₂O₃ is promoted by unsaturated CH₂ ends