A combined scheme of parallel-reaction kinetic model and multi-layer artificial neural network model on pyrolysis of Reed Canary

A comprehensive understanding of pyrolysis kinetics is crucial for the design of biomass pyrolysis. In this study, a combined scheme was proposed for biomass pyrolysis. A kinetic model, serving as a knowledge-based model, was established to capture the primary trend of biomass pyrolysis. An ANN model, as an experience-based model, was developed to provide "details" on the process. The kinetic model incorporated a least-square optimization model to calculate optimal kinetic parameters for pyrolysis reaction steps. The ANN model utilized metaheuristic algorithms such as Particle Swarm Optimization, Pattern Search, Genetic Algorithms, and Surrogate Optimization to optimize the hyperparameters of the ANN model. By combining the kinetic model with the ANN model, comprehensive predictions of biomass pyrolysis were obtained, and the combined Kinetic-ANN model was validated with experimental data at 4 heating rates. Finally, the combined model was compared with the solokinetic and solo-ANN models, confirming the advanced performance of the combined approach.