Stereoselective alkyl C-glycosylation of glycosyl esters via anomeric C–O bond homolysis: efficient access to C-glycosyl amino acids and C-glycosyl peptides

Anrong Chen,Shiyin Zhao,Yujie Han,Zhenghong Zhou,Bo Yang,Lan‐Gui Xie,M Walczak,Feng Zhu

Chemical Science（2023）

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摘要

A novel photoredox-catalyzed radical conjugate addition of 1,4-dihydropyridine-derived glycosyl esters and dehydroalanine derivatives via anomeric C(sp 3 )–O bond homolysis to construct C -glycosyl amino acids and peptides is for the first time described.

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关键词

<i>c</i>-glycosylation esters,peptides,amino acids,alkyl

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