Chelated O₂BOH^2– or Chelated O₂CO^2–: An Isoelectronic Conundrum

Fouad Ismael,Cassandra L. Fleming,Lawrence R. Gahan,Allan G. Blackman

Inorganic Chemistry（2023）

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摘要

The species originally reported as [Co(bipy)2O2BOH]·[B5O6(OH)4]·H3BO3·H3O·H2O, a Co(II) complex containing a chelated O2BOH2- ligand, is shown to be [Co(bipy)2O2CO]·[B5O6(OH)4]·H3BO3·2H2O, a Co(III) complex containing a chelated O2CO2- ligand. This was confirmed by 1H and 13C NMR, MS, IR, and an X-ray crystal structure.

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isoelectronic conundrum

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Chelated O2BOH2– or Chelated O2CO2–: An Isoelectronic Conundrum

Chelated O₂BOH^2– or Chelated O₂CO^2–: An Isoelectronic Conundrum