Design and synthesis of dinuclear cobalt(ii) complexes derived from strong π-acidic ligands: crystal structure and studies on the oxidation of sp³ C–H bonds

Avtar Singh,Bishal Boro,Ankur Maji,Ovender Singh,Sain Singh, U. P. Singh,Kaushik Ghosh

New Journal of Chemistry（2023）

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摘要

Cobalt complexes (1 and 2) supported by strong π-acidic ligands were synthesized and characterized. These complexes were employed as catalysts for the oxidation of sp 3 C–H bonds. Mechanistic pathways are proposed on the basis of experimental evidence.

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ligands,cobalt<scp>ii</scp>,complexes,synthesis

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Design and synthesis of dinuclear cobalt(ii) complexes derived from strong π-acidic ligands: crystal structure and studies on the oxidation of sp3 C–H bonds

Design and synthesis of dinuclear cobalt(ii) complexes derived from strong π-acidic ligands: crystal structure and studies on the oxidation of sp³ C–H bonds