Chemical Prepotassiation Realizes Scalable KC₈ Foil Anodes for Potassium‐Ion Pouch Cells

Abstract Currently, graphite (Gr) and potassium metal are two typical and widely used anodes for potassium‐ion batteries (PIBs). Unfortunately, the inevitable electrochemical prepotassiation of Gr anode and the unprocessable nature of K metal hinder the advancement of potassium‐ion pouch cells. There is an urgent need to develop alternative anodes for promoting the practical applications of PIBs. Herein, KC 8 is proposed as a specialized anode for the research of PIBs. By taking a chemical prepotassiation strategy, a large‐area KC 8 foil is successfully fabricated for the first time. Through molecularly tailoring K‐arene complex, the Gibb's free energy of the Gr prepotassiation reaction can be changed, thus enabling accurate preparation of pure‐phase KC 8 .The size‐controllable KC 8 anode exhibits a high areal capacity of 1.49 mAh cm −2 comparable to the commercial Gr anode used in lithium‐ion batteries. Based on this, a stackable pouch cell delivers an unprecedented high capacity of 106 mAh and high energy density >100 Wh kg −1 cathode+anode . This work highlights the prospect of scalable KC 8 foil anodes to achieve practical PIBs.