Microwave-assisted chemoselective transamidation of secondary amides by selective N–C(O) bond cleavage under catalyst, additive and solvent-free conditions

Vishal Singh, Khushbu Rajput,Ankush Mishra,Sundaram Singh,Vandana Srivastava

Chemical Communications（2023）

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摘要

An efficient environmentally friendly microwave-assisted approach under catalyst, additive and solvent-free conditions for the N -Boc-activated secondary amide transamidation via tetrahedral intermediate was developed.

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关键词

chemoselective transamidation,secondary amides,bond cleavage,microwave-assisted,solvent-free

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