Sodiation energetics in pore size controlled hard carbons determined via entropy profiling

Michael Mercer,Mangayarkarasi Nagarathinam, Edgardo Maximiliano Gavilán Arriazu, Anshika Binjrajka, Swoyam Panda,Heather Au,Maria Crespo‐Ribadeneyra,Maria‐Magdalena Titirici, E.P.M. Leiva,Harry E. Hoster

Journal of materials chemistry. A, Materials for energy and sustainability（2023）

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摘要

Cell temperature of hard carbons is varied under open circuit conditions (entropy profiling) during sodiation. Features vary with pore size, revealing the nanopore filling onset. Sodium binding energy scales inversely with pore curvature radius.

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关键词

hard carbons,pore size,energetics

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